Key: Win : Draw : Loss
| Date | Home | Away | Ref | ||
|---|---|---|---|---|---|
| 03/08/2013 | Port Vale | 1 | 1 | Brentford | S Bratt |
| 10/08/2013 | Colchester | 1 | 0 | Port Vale | D Deadman |
| 17/08/2013 | Port Vale | 2 | 1 | Bradford | C Boyeson |
| 24/08/2013 | Oldham | 3 | 1 | Port Vale | C Sarginson |
| 31/08/2013 | Port Vale | 1 | 3 | Wolves | G Scott |
| 07/09/2013 | Carlisle | 0 | 1 | Port Vale | M Brown |
| 14/09/2013 | Leyton Orient | 3 | 2 | Port Vale | M Russell |
| 21/09/2013 | Port Vale | 3 | 2 | Coventry | M Naylor |
| 28/09/2013 | Tranmere | 0 | 1 | Port Vale | P Tierney |
| 05/10/2013 | Port Vale | 1 | 1 | Bristol City | S Stockbridge |
| 12/10/2013 | Port Vale | 0 | 1 | Peterboro | M Bull |
| 19/10/2013 | Sheffield United | 2 | 1 | Port Vale | T Robinson |
| 22/10/2013 | Crawley Town | 0 | 3 | Port Vale | F Graham |
| 26/10/2013 | Port Vale | 2 | 1 | Gillingham | D Bond |
| 02/11/2013 | Swindon | 5 | 2 | Port Vale | A Woolmer |
| 16/11/2013 | Port Vale | 3 | 1 | Shrewsbury | C Boyeson |
| 23/11/2013 | Crewe | 1 | 2 | Port Vale | G Salisbury |
| 26/11/2013 | Port Vale | 0 | 2 | Preston | A Madley |
| 30/11/2013 | Walsall | 0 | 2 | Port Vale | M Naylor |
| 14/12/2013 | Port Vale | 2 | 2 | Stevenage | G Eltringham |
| 21/12/2013 | Milton Keynes Dons | 3 | 0 | Port Vale | E Ilderton |
| 26/12/2013 | Port Vale | 2 | 1 | Notts County | O Langford |
| 29/12/2013 | Port Vale | 2 | 0 | Rotherham | R Lewis |
| 01/01/2014 | Preston | 3 | 2 | Port Vale | K Wright |
| 11/01/2014 | Brentford | 2 | 0 | Port Vale | P Gibbs |
| 18/01/2014 | Port Vale | 1 | 0 | Oldham | G Sutton |
| 01/02/2014 | Gillingham | 3 | 2 | Port Vale | D Deadman |
| 08/02/2014 | Port Vale | 2 | 3 | Swindon | S Stockbridge |
| 11/02/2014 | Port Vale | 2 | 0 | Colchester | A Haines |
| 15/02/2014 | Shrewsbury | 0 | 0 | Port Vale | J Adcock |
| 18/02/2014 | Bradford | 1 | 0 | Port Vale | M Brown |
| 22/02/2014 | Port Vale | 1 | 3 | Crewe | R East |
| 01/03/2014 | Wolves | 3 | 0 | Port Vale | C Pawson |
| 08/03/2014 | Port Vale | 2 | 1 | Carlisle | S Duncan |
| 11/03/2014 | Port Vale | 0 | 2 | Leyton Orient | J Simpson |
| 16/03/2014 | Coventry | 2 | 2 | Port Vale | R Lewis |
| 22/03/2014 | Port Vale | 3 | 2 | Tranmere | R Clark |
| 25/03/2014 | Bristol City | 5 | 0 | Port Vale | K Hill |
| 29/03/2014 | Stevenage | 1 | 1 | Port Vale | C Breakspear |
| 01/04/2014 | Port Vale | 2 | 1 | Crawley Town | N Miller |
| 05/04/2014 | Port Vale | 1 | 0 | Walsall | C Berry |
| 12/04/2014 | Notts County | 4 | 2 | Port Vale | D Drysdale |
| 18/04/2014 | Port Vale | 1 | 0 | Milton Keynes Dons | A Madley |
| 21/04/2014 | Rotherham | 1 | 0 | Port Vale | D Coote |
| 25/04/2014 | Port Vale | 1 | 2 | Sheffield United | S Bratt |
| 03/05/2014 | Peterboro | 0 | 0 | Port Vale | J Simpson |